Mechanism of solid-state clumped isotope reordering in carbonate minerals from aragonite heating experiments
نویسندگان
چکیده
منابع مشابه
Solid‐State Transformation of Amorphous Calcium Carbonate to Aragonite Captured by CryoTEM
Early-stage reaction mechanisms for aragonite-promoting systems are relatively unknown compared to the more thermodynamically stable calcium carbonate polymorph, calcite. Using cryoTEM and SEM, the early reaction stages taking place during aragonite formation were identified in a highly supersaturated solution using an alcohol-water solvent, and an overall particle attachment growth mechanism w...
متن کاملInfluence of climate change and uplift on Colorado Plateau paleotemperatures from carbonate clumped isotope thermometry
[1] The elevation history of Earth’s surface is key to understanding the geodynamic processes responsible for the rise of plateaus. We investigate the timing of Colorado Plateau uplift by estimating depositional temperatures of Tertiary lake sediments that blanket the plateau interior and adjacent lowlands using carbonate clumped isotope paleothermometry (a measure of the temperature‐dependent ...
متن کاملStatistical clumped isotope signatures
High precision measurements of molecules containing more than one heavy isotope may provide novel constraints on element cycles in nature. These so-called clumped isotope signatures are reported relative to the random (stochastic) distribution of heavy isotopes over all available isotopocules of a molecule, which is the conventional reference. When multiple indistinguishable atoms of the same e...
متن کاملClumped isotope measurements of small carbonate samples using a high-efficiency dual-reservoir technique.
RATIONALE The measurement of multiply substituted isotopologues of CO2 derived from carbonate has allowed the reconstruction of paleotemperatures from a single phase (CaCO3 ), circumventing uncertainty inherent in other isotopic paleothermometers. Traditional analytical techniques require relatively large amounts of carbonate (3-8 mg per replicate), which limits the applicability of the clumped...
متن کاملCarbonate clumped isotope thermometry of deep-sea corals and implications for vital effects
Here we calibrate the carbonate clumped isotope thermometer in modern deep-sea corals. We examined 11 specimens of three species of deep-sea corals and one species of a surface coral spanning a total range in growth temperature of 2–25 C. External standard errors for individual measurements ranged from 0.005& to 0.011& (average: 0.0074&) which corresponds to 1–2 C. External standard errors for ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Geochimica et Cosmochimica Acta
سال: 2019
ISSN: 0016-7037
DOI: 10.1016/j.gca.2019.05.018